Real-time tracking of ionic nano-domains under shear flow.

ABSTRACT: The behaviour of ions at solid-liquid interfaces underpins countless phenomena, from the conduction of nervous impulses to charge transfer in solar cells. In most cases, ions do not operate as isolated entities, but in conjunction with neighbouring ions and the surrounding solution. In aqueous solutions, recent studies suggest the existence of group dynamics through water-mediated clusters but results allowing direct tracking of ionic domains with atomic precision are scarce. Here, we use high-speed atomic force microscopy to track the evolution of Rb⁺, K⁺, Na⁺ and Ca²⁺ nano-domains containing 20 to 120 ions adsorbed at the surface of mica in aqueous solution. The interface is exposed to a shear flow able to influence the lateral motion of single

SUBMITTER: Cafolla C 

PROVIDER: S-EPMC8486851 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature