Polymeric coordination complex of lithium(I) with aqua and cyanurate ligands.

ABSTRACT: The polymeric title complex, poly[hexa-μ-aqua-diaquatetra-μ-cyanurato-tetralithium] [Li₄(C₃H₂N₃O₃)₄(H₂O)₇] _n , synthesized at room temperature from an aqueous solution of lithium hydroxide and cyanuric chloride, crystallizes in the triclinic space group P . There are two distinct Li⁺ cations in the asymmetric unit, one of which, Li1, has distorted trigonal-bipyramidal geometry and is coordinated via oxygen to two cyanurate anions occupying equatorial positions, and three water mol-ecules, two in the axial positions and the third in an equatorial position. One of the axial water ligands and the equatorial water ligand are involved in bridging to a crystallograph

SUBMITTER: Ponnuvel A 

PROVIDER: S-EPMC8491521 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature