Crystal structure of the new palladium complexes tetra-kis-(1,3-di-methyl-imidazolium-2-yl-idene)palladium(II) hexa-deca-carbonyl-tetra-rhenium diethyl ether disolvate and octa-μ-carbonyl-di-carbonyl-tetra-kis-(tri-phenyl-phosphane)palladium-dirhenium (unknown solvate).

ABSTRACT: The investigation of the coordination chemistry of heterometallic transition-metal complexes of palladium (Pd) and rhenium (Re) led to the isolation and crystallographic characterization of tetra-kis-(1,3-di-methyl-imidazolium-2-yl-idene)palladium(II) hexa-deca-carbonyl-tetra-rhenium diethyl ether disolvate, [Pd(C₅H₈N₂)₄][Re₄(CO)₁₆]·2C₄H₁₀O or [Pd(IMe)₄][Re₄(CO)₁₆]·2C₄H₁₀O, (1), and octa-μ-carbonyl-di-carbonyl-tetra-kis-(tri-phenyl-phosphane)palladium-dirhenium, [Pd₄Re₂(C₁₈H₁₅P)₄(CO)₁₀] or Pd₄Re₂(PPh₃)₄(μ-CO)₈(CO)₂

SUBMITTER: Shapovalov S 

PROVIDER: S-EPMC8491523 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature