Crystal structure of [Th₃(Cp*)₃(O)(OH)₃]₂Cl₂(N₃)₆: a discrete mol-ecular capsule built from multinuclear organothorium cluster cations.

ABSTRACT: An unusually large and structurally complex charge-neutral polynuclear cluster, hexa-μ₂-azido-di-μ₃-chlorido-hexa-μ₂-hydroxido-di-μ₃-oxido-hexa-kis-(penta-methyl-cyclo-penta-dien-yl)hexa-thorium-diethyl ether-tetra-hydro-furan (1/0.56/1.44), [Th₃(C₁₀H₁₅)₆Cl₃(N₃)₆(OH)₆O₂]·0.56C₄H₁₀O·1.44C₄H₈O or [Th₃(Cp*)₃(O)(OH)₃]₂Cl₂(N₃)₆·0.56C₄H₁₀O·1.44C₄H₈O (Cp* = [penta-methyl-cyclo-penta-dien-yl])^-, has been crystallized as a mixed tetra-hydro-furan/diethyl ether solvate and structurally

SUBMITTER: Kelley SP 

PROVIDER: S-EPMC8491527 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature