Crystal structure of caesium tetra-methyl-dithio-imidodiphosphinate.

ABSTRACT: In the title crystal, the salt [CsMe₂P(S)NP(S)Me₂] is self-assembled as an undulating supra-molecular two-dimensional polymeric structure, poly[(μ₄-tetra-methyl-dithio-imidodiphosphinato)caesium], [Cs(C₄H₁₂NP₂S₂)] _n , which is parallel to the bc plane. The Cs cations are hexa-coordinated, being chelated by two thio-imidophosphinate groups and two sulfur atoms from neighboring ligands. The anions are linked to the Cs cations by Cs⋯S and Cs⋯N electrostatic inter-actions.

SUBMITTER: Lopez-Cardoso M 

PROVIDER: S-EPMC8491530 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature