Dataset Information

SiO _x /C Composite Anode of Lithium-Ion Batteries with Enhanced Performances Using Multicomponent Binders.

ABSTRACT: A silicon suboxide-carbon (SiO _x /C, 1 ≤ x ≤ 2) composite anode of lithium-ion batteries (LIBs) with enhanced performance is prepared using an aqueous multicomponent binder technology. Considering the adhesive force, electrolyte absorption, and stability, different binders including sodium alginate (SA), polyacrylamide gel (PAM), polytetrafluoroethylene (PTFE), and their composites are evaluated. It is indicated that compared to other anodes with single- or multicomponent binders, the SiO _x /C composite anode with PAM/SA/PTFE663 (PSAP663) binders exhibits strong adhesion, moderate electrolyte absorption ability, and a specific capacity of 427 mA h g^-1 charge-discharged at 0.5 A g^-1 after 300 cycles. The improvement of electrochemical performance is attributed to the comprehensive effects of composite binders, including the adhesion of active substances, surface protection, solution adsorption, conductive path, and so on. These results show that the PSAP663 binder has promising potential for application, which not only gives alternative practical schemes of the green binders for the SiO _x /C anodes but also provides ideas to develop a high-performance adhesive technology for LIBs.

SUBMITTER: Liu H

PROVIDER: S-EPMC8515830 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature

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SiO x /C Composite Anode of Lithium-Ion Batteries with Enhanced Performances Using Multicomponent Binders.

Liu Haoyuan H Huangzhang Encheng E Sun Chenhao C Fan Yanchao Y Ma Zhen Z Zhao Xiaoyang X Nan Junmin J

ACS omega 20211001 40

A silicon suboxide-carbon (SiO x /C, 1 ≤ x ≤ 2) composite anode of lithium-ion batteries (LIBs) with enhanced performance is prepared using an aqueous multicomponent binder technology. Considering the adhesive force, electrolyte absorption, and stability, different binders including sodium alginate (SA), polyacrylamide gel (PAM), polytetrafluoroethylene (PTFE), and their composites are evaluated. It is indicated that compared to other anodes with single- or multicomponen ...[more]

PMID: 34661035

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Project description:Bagasse-derived carbon electrodes were developed by doping with nitrogen functional groups and compositing with high-capacity MnO2 nanoparticles (MnO2/NBGC). The bagasse-derived biochar was N-doped by refluxing in urea, followed by the deposition of MnO2 nanoparticles onto its porous surface via the hydrothermal reduction of KMnO4. Different initial KMnO4 loading concentrations (i.e. 5, 10, 40, and 100 mM) were applied to optimize the composite morphology and the corresponding electrochemical performance. Material characterization confirmed that the carbon composite has a mesoporous structure along with the dispersion of MnO2 nano-particles on the N-containing carbon surface. It was found that the 5-MnO2/NBGC sample exhibited the highest electrochemical performance with a reversible capacity of 760 mA h g-1 at a current density of 186 mA g-1. It delivered reversible capacities of 488 and 390 mA h g-1 in cycle tests at 372 and 744 mA g-1, respectively, for 150 cycles and presented good reversibility with nearly 100% coulombic efficiency. In addition, it could exert high capacities up to 388 and 301 mA h g-1 even under high current densities of 1860 and 3720 mA g-1, respectively. Moreover, most of the prepared composite products showed high rate capability with great reversibility up to more than 90% after testing at a high current density of 3720 mA g-1. The great electrochemical performance of the MnO2/NBGC nanocomposite electrode can be attributed to the synergistic impact of the hierarchical architecture of the MnO2 nanocrystals deposited on porous carbon and the capacitive effect of the N-containing defects within the carbon material. The nanostructure of the MnO2 particles deposited on porous carbon limits its large volume change during cycling and promotes good adhesion of MnO2 nanoparticles with the substrate. Meanwhile, the capacitive effect of the exposed N-functional groups enables fast ionic conduction and reduces interfacial resistance at the electrode interface.

Dataset Information

SiO _x /C Composite Anode of Lithium-Ion Batteries with Enhanced Performances Using Multicomponent Binders.

Publications

SiO <sub><i>x</i></sub> /C Composite Anode of Lithium-Ion Batteries with Enhanced Performances Using Multicomponent Binders.

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