Direct Detection of Surface Species Formed on Iridium Electrocatalysts during the Oxygen Evolution Reaction.

ABSTRACT: The effect of surface orientations on the formation of iridium oxide species during the oxygen evolution reaction (OER) remains yet unknown. Herein, we use a needle-shaped iridium atom probe specimen as a nanosized working electrode to ascertain the role of the surface orientations in the formation of oxide species during OER. At the beginning of electrolysis, the top 2-3 nm of (024), (026), (113), and (115) planes are covered by IrO-OH, which activates all surfaces towards OER. A thick subsurface oxide layer consisting of sub-stoichiometric Ir-O species is formed on the open (024) planes as OER proceeds. Such metastable Ir-O species are thought to provide an additional contribution to the OER activity. Overall, this study sheds light on the importance of the morphological effects of iridi

SUBMITTER: BalaKrishnan A 

PROVIDER: S-EPMC8518547 | biostudies-literature | 2021 Sep

REPOSITORIES: biostudies-literature