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Single-Use Fluidic Electrochemical Paper-Based Analytical Devices Fabricated by Pen Plotting and Screen-Printing for On-Site Rapid Voltammetric Monitoring of Pb(II) and Cd(II).

ABSTRACT: This work reports the fabrication of integrated electrochemical fluidic paper-based analytical devices (ePADs) using a marker pen drawing and screen-printing. Electrodes were deposited on paper using screen-printing with conductive carbon ink. Then, the desired fluidic patterns were formed on the paper substrate by drawing with a commercial hydrophobic marker pen using an inexpensive computer-controlled x-y plotter. The working electrode was characterized by cyclic voltammetry and scanning electron microscopy. The analytical utility of the electrochemical PADs is demonstrated through electrochemical determination of Pb(II) and Cd(II) by anodic stripping voltammetry. For this purpose, the sample was mixed with a buffer solution and a Bi(III) solution, applied to the test zone of the PAD, the metals were preconcentrated as a bismuth alloy on the electrode surface and oxidized by applying an anodic potential scan. The proposed manufacturing approach enables the large-scale fabrication of fit-for-purpose disposable PADs at low cost which can be used for rapid on-site environmental monitoring.

SUBMITTER: Soulis D

PROVIDER: S-EPMC8539493 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature

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Single-Use Fluidic Electrochemical Paper-Based Analytical Devices Fabricated by Pen Plotting and Screen-Printing for On-Site Rapid Voltammetric Monitoring of Pb(II) and Cd(II).

Soulis Dionysios D Trachioti Maria M Kokkinos Christos C Economou Anastasios A Prodromidis Mamas M

Sensors (Basel, Switzerland) 20211018 20

This work reports the fabrication of integrated electrochemical fluidic paper-based analytical devices (ePADs) using a marker pen drawing and screen-printing. Electrodes were deposited on paper using screen-printing with conductive carbon ink. Then, the desired fluidic patterns were formed on the paper substrate by drawing with a commercial hydrophobic marker pen using an inexpensive computer-controlled x-y plotter. The working electrode was characterized by cyclic voltammetry and scanning elect ...[more]

PMID: 34696121

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Project description:BackgroundThe natural polyether ionophorous antibiotics are used for the treatment of coccidiosis in poultry and ruminants. They are effective agents against infections caused by Gram-positive microorganisms. On the other hand, it was found that some of these compounds selectively bind lead(II) ions in in vivo experiments, despite so far no Pb(II)-containing compounds of defined composition have been isolated and characterized. To assess the potential of polyether ionophores as possible antidotes in the agriculture, a detailed study on their in vitro complexation with toxic metal ions is required. In the present paper we report for the first time the preparation and the structure elucidation of salinomycin complexes with ions of cadmium(II) and lead(II).ResultsNew metal(II) complexes of the polyether ionophorous antibiotic salinomycin with Cd(II) and Pb(II) ions were prepared and structurally characterized by IR, FAB-MS and NMR techniques. The spectroscopic information and elemental analysis data reveal that sodium salinomycin (SalNa) undergoes a reaction with heavy metal(II) ions to form [Cd(Sal)2(H2O)2] (1) and [Pb(Sal)(NO3)] (2), respectively. Abstraction of sodium ions from the cavity of the antibiotic is occurring during the complexation reaction. Salinomycin coordinates with cadmium(II) ions as a bidentate monoanionic ligand through the deprotonated carboxylic moiety and one of the hydroxyl groups to yield 1. Two salinomycin anions occupy the equatorial plane of the Cd(II) center, while two water molecules take the axial positions of the inner coordination sphere of the metal(II) cation. Complex 2 consists of monoanionic salinomycin acting in polydentate coordination mode in a molar ratio of 1: 1 to the metal ion with one nitrate ion for charge compensation.ConclusionThe formation of the salinomycin heavy metal(II) complexes indicates a possible antidote activity of the ligand in case of chronic/acute intoxications likely to occur in the stock farming.

Dataset Information

Single-Use Fluidic Electrochemical Paper-Based Analytical Devices Fabricated by Pen Plotting and Screen-Printing for On-Site Rapid Voltammetric Monitoring of Pb(II) and Cd(II).

Publications

Single-Use Fluidic Electrochemical Paper-Based Analytical Devices Fabricated by Pen Plotting and Screen-Printing for On-Site Rapid Voltammetric Monitoring of Pb(II) and Cd(II).

Similar Datasets

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