Synthesis of Si/Fe2O3-Anchored rGO Frameworks as High-Performance Anodes for Li-Ion Batteries.

ABSTRACT: By virtue of the high theoretical capacity of Si, Si-related materials have been developed as promising anode candidates for high-energy-density batteries. During repeated charge/discharge cycling, however, severe volumetric variation induces the pulverization and peeling of active components, causing rapid capacity decay and even development stagnation in high-capacity batteries. In this study, the Si/Fe2O3-anchored rGO framework was prepared by introducing ball milling into a melt spinning and dealloying process. As the Li-ion battery (LIB) anode, it presents a high reversible capacity of 1744.5 mAh g-1 at 200 mA g-1 after 200 cycles and 889.4 mAh g-1 at 5 A g-1 after 500 cycles. The outstanding electrochemical performance is due to the three-dimensional cross-linked porous framework wit

SUBMITTER: Yan Y 

PROVIDER: S-EPMC8539548 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature