ABSTRACT: A series of new complexes, [Ln (2,4-DMBA)3(5,5'-DM-2,2'-bipy)]2 (Ln = Sm(1), Eu (2)), [Pr (2,4-DMBA)3 (5,5'-DM-2,2'-bipy)]2·0.5(C2H5OH) (3), [Ln (2,4-DMBA)3 (5,5'-DM-2,2'-bipy)]2·0.5(2,4-DMBAH)·0.25(5,5'-DM-2,2'-bipy) (Ln = Tb (4), Dy (5)) (2,4-DMBA = 2,4-dimethylbenzoate, 5,5'-DM-2,2'-bipy = 5,5'-dimethy-2,2'-bipyridine) were synthesized via hydrothermal reaction conditions. The complexes were characterized through elemental analysis, Infrared spectra (IR), Raman (R) spectra, UV-Vis spectra, single X-ray diffraction. Single crystal data show that complexes 1-5 are binuclear complexes, but they can be divided into three different crystal structures. The thermal decomposition mechanism of c
