Vibrationally excited molecular hydrogen production from the water photochemistry.

ABSTRACT: Vibrationally excited molecular hydrogen has been commonly observed in the dense photo-dominated regions (PDRs). It plays an important role in understanding the chemical evolution in the interstellar medium. Until recently, it was widely accepted that vibrational excitation of interstellar H₂ was achieved by shock wave or far-ultraviolet fluorescence pumping. Here we show a further pathway to produce vibrationally excited H₂ via the water photochemistry. The results indicate that the H₂ fragments identified in the O(¹S) + H₂(X¹Σ_g⁺) channel following vacuum ultraviolet (VUV) photodissociation of H₂O in the wavelength range of λ = ~100-112 nm are vibrationally excited. In particular, more than

SUBMITTER: Chang Y 

PROVIDER: S-EPMC8563719 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature