Construction of solid-liquid fluorine transport channel to enable highly reversible conversion cathodes.

ABSTRACT: Conversion-type iron fluoride is a promising alternative cathode to intercalation oxides because of its higher energy density. However, its intrinsic solid-solid conversion is sluggish during repeated splitting and rebonding of metal-fluorine moieties. Here, we propose a solid-liquid conversion mechanism to activate the fluorine transport kinetics of iron oxyfluorides enabled by fluoride anion receptor of tris(pentafluorophenyl)borane (TPFPB). TPFPB promotes the dissociation of inert lithium fluoride and provides a facile fluorine transport channel at multiphase interfaces via the formation of solvated F⁻ intermediate therein. The construction of solid-liquid channel with fluorinated cathode electrolyte interface is the key for the achievement of FeO_0.3F_1.7 and FeO_0.7F_1.3 in terms of sustaining conversion reaction (with an energy efficiency approaching 80%) and high-rate performance (with reversible capacity of 320 mAh/g at 2 A/g). The cathode energy densities can reach 1100 Wh/kg for FeO_0.3F_1.7 and 700 Wh/kg for FeO_0.7F_1.3 under the power densities of 220 and 4300 W/kg, respectively.

SUBMITTER: Chen K 

PROVIDER: S-EPMC8565847 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature