Comparison of homogeneous and heterogeneous catalysts in dye-sensitised photoelectrochemical cells for alcohol oxidation coupled to dihydrogen formation.

ABSTRACT: This study examines two strategies-homo- and heterogeneous approaches for the light-driven oxidation of benzyl alcohol in dye-sensitised photoelectrochemical cells (DSPECs). The DSPEC consists of a mesoporous anatase TiO2 film on FTO (fluorine-doped tin oxide), sensitised with the thienopyrroledione-based dye AP11 as the photoanode and an FTO-Pt cathode combined with a redox-mediating catalyst. The homogeneous catalyst approach entails the addition of the soluble 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) to the DSPEC anolyte, while the heterogeneous strategy employs immobilisation of a TEMPO analogue with a silatrane anchor (S-TEMPO) onto the photoanode. Irradiation of the photoanode oxidises the TEMPO-moiety to TEMPO+, both in the homogeneous and the heterogeneous system, which is a ch

SUBMITTER: Bruggeman DF 

PROVIDER: S-EPMC8577521 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature