Rules of hierarchical melt and coordinate bond to design crystallization in doped phase change materials.

ABSTRACT: While alloy design has practically shown an efficient strategy to mediate two seemingly conflicted performances of writing speed and data retention in phase-change memory, the detailed kinetic pathway of alloy-tuned crystallization is still unclear. Here, we propose hierarchical melt and coordinate bond strategies to solve them, where the former stabilizes a medium-range crystal-like region and the latter provides a rule to stabilize amorphous. The Er_0.52Sb₂Te₃ compound we designed achieves writing speed of 3.2 ns and ten-year data retention of 161 °C. We provide a direct atomic-level evidence that two neighbor Er atoms stabilize a medium-range crystal-like region, acting as a precursor to accelerate crystallization; meanwhile, the stabilized amorphous orig

SUBMITTER: Zhao J 

PROVIDER: S-EPMC8578292 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature