Visible light-induced oxidative N-dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex.

ABSTRACT: N-Dealkylation of amines by metal oxo intermediates (M[double bond, length as m-dash]O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N-dealkylation of various alkylamines by a luminescent osmium(vi) nitrido complex induced by visible light.

SUBMITTER: Xiang J 

PROVIDER: S-EPMC8580045 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature