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Effect of Extending the Conjugation of Dye Molecules on the Efficiency and Stability of Dye-Sensitized Solar Cells.

ABSTRACT: We designed and synthesized two organic dyes (A6 and A10) for dye-sensitized solar cells (DSSCs) by extending the molecular conjugation strategy. The sensitizer A10 was constructed by inserting ethene into our previously reported sensitizer AZ6. The sensitizer A6 was obtained by further substituting the hydrogen of ethene with another donor (D) and π-bridge-acceptor (π-A) segment. The UV-vis spectra and J-V curves showed that the dyes A10 and A6 could effectively facilitate the light-harvesting and photocurrent densities with respect to AZ6. Consequently, the A10-based DSSC achieved an enhanced efficiency (8.54%) with a high photocurrent (18.81 mA cm^-2). Desorption experiments of dyes adsorbed on TiO₂ showed that compared with the monoanchoring dyes AZ6 and A10, the dianchoring configuration effectively strengthened the affinity of dye A6 with the photoanode, making it more difficult to leach from the photoanode. The A6-based DSSC shows outstanding stability, and its overall efficiency could remain 98.0% of its initial value after 3000 h of aging time, exceeding that of its monoanalogue AZ6 (remained 78.3% after 3000 h).

SUBMITTER: Zhou P

PROVIDER: S-EPMC8582274 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature

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Effect of Extending the Conjugation of Dye Molecules on the Efficiency and Stability of Dye-Sensitized Solar Cells.

Zhou Pengjuan P Lin Bobing B Chen Ran R An Zhongwei Z Chen Xinbing X An Qi Q Chen Pei P

ACS omega 20211027 44

We designed and synthesized two organic dyes (A6 and A10) for dye-sensitized solar cells (DSSCs) by extending the molecular conjugation strategy. The sensitizer A10 was constructed by inserting ethene into our previously reported sensitizer AZ6. The sensitizer A6 was obtained by further substituting the hydrogen of ethene with another donor (D) and π-bridge-acceptor (π-A) segment. The UV-vis spectra and J-V curves showed that the dyes A10 and A ...[more]

PMID: 34778678

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Project description:Herein, we present a thorough photovoltaic investigation of four triphenylamine organic sensitizers with D-π-A configurations and compare their photovoltaic performances to the conventional ruthenium-based sensitizer N719. SFA-5-8 are synthesized and utilized as sensitizers for dye-sensitized solar cell (DSSC) applications. The effects of the donor unit (triphenylamine), π-conjugation bridge (thiophene ring), and various acceptors (phenylacetonitrile and 2-cyanoacetamide derivatives) were investigated. Moreover, this was asserted by profound calculations of HOMO (highest occupied molecular orbital) and LUMO (lowest unoccupied molecular orbital) energy levels, the molecular electrostatic potential (MEP), and natural bond orbital (NBO) that had been studied for the TPA-sensitizers. Theoretical density functional theory (DFT) was performed to study the distribution of electron density between donor and acceptor moieties. The sensitization by the absorption of sensitizers SFA-5-8 leads to an obvious enhancement in the visible light absorption (300-750 nm) as well as a higher photovoltaic efficiency in the range of (5.53-7.56%). Under optimized conditions, SFA-7 showed outstanding sensitization of nanocrystalline TiO2, resulting in enhancing the visible light absorption and upgrading the power conversion efficiency (PCE) to approximately 7.56% over that reported for the N719 (7.29%). Remarkably, SFA-7 outperformed N719 by 4% in the total conversion efficiency. Significantly, the superior performance of SFA-7 could be mainly ascribed to the higher short-circuit photocurrents (Jsc) in parallel with larger open-circuit voltages (Voc) and more importantly, the presence of different anchoring moieties that could enhance the ability to fill the gaps on the surface of the TiO2 semiconductor. That could be largely reflected in the overall enhancement in the device efficiency. Moreover, the theoretical electronic and photovoltaic properties of all studied sensitizers have been compared with experimental results. All the 2-cyanoacrylamide derivative sensitizers demonstrated robust photovoltaic performance.

Dataset Information

Effect of Extending the Conjugation of Dye Molecules on the Efficiency and Stability of Dye-Sensitized Solar Cells.

Publications

Effect of Extending the Conjugation of Dye Molecules on the Efficiency and Stability of Dye-Sensitized Solar Cells.

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