Effect of Extending the Conjugation of Dye Molecules on the Efficiency and Stability of Dye-Sensitized Solar Cells.

ABSTRACT: We designed and synthesized two organic dyes (A6 and A10) for dye-sensitized solar cells (DSSCs) by extending the molecular conjugation strategy. The sensitizer A10 was constructed by inserting ethene into our previously reported sensitizer AZ6. The sensitizer A6 was obtained by further substituting the hydrogen of ethene with another donor (D) and π-bridge-acceptor (π-A) segment. The UV-vis spectra and J-V curves showed that the dyes A10 and A6 could effectively facilitate the light-harvesting and photocurrent densities with respect to AZ6. Consequently, the A10-based DSSC achieved an enhanced efficiency (8.54%) with a high photocurrent (18.81 mA cm^-2). Desorption experiments of dyes adsorbed on TiO₂

SUBMITTER: Zhou P 

PROVIDER: S-EPMC8582274 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature