Unknown

Dataset Information

0

Syntheses and crystal structures of two copper(I)-halide π,σ-coordination compounds based on 2-[(prop-2-en-1-yl)sulfan-yl]pyridine.

ABSTRACT: The title compounds, di-μ-chlorido-bis-({2-[(η-2,3)-(prop-2-en-1-yl)sulfan-yl]pyridine-κN}copper(I)), [Cu2Cl2(C8H9NS)2], and di-μ-bromido-bis-({2-[(η-2,3)-(prop-2-en-1-yl)sulfan-yl]pyridine-κN}copper(I)), [Cu2Br2(C8H9NS)2], were obtained by alternating-current electrochemical synthesis starting from an ethano-lic solution of 2-[(prop-2-en-1-yl)sulfan-yl]pyridine (Psup) and the copper(II) halide. The isostructural crystals are built up from centrosymmetric [Cu2 Hal 2(Psup)2] dimers, which are formed due to the π,σ-chelating behavior of the organic ligand. In the crystals, the dimers are linked by C-H⋯Hal hydrogen bonds as well as by aromatic π-π stacking inter-actions into a three-dimensional network.

SUBMITTER: Slyvka Y 

PROVIDER: S-EPMC8587979 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Syntheses and crystal structures of two copper(I)-halide π,σ-coordination compounds based on 2-[(prop-2-en-1-yl)sulfan-yl]pyridine.

Slyvka Yurii Y   Pokhodylo Nazariy T NT   Goreshnik Evgeny E   Pavlyuk Olexii O   Mys'kiv Marian M  

Acta crystallographica. Section E, Crystallographic communications 20211029 Pt 11

The title compounds, di-μ-chlorido-bis-({2-[(η-2,3)-(prop-2-en-1-yl)sulfan-yl]pyridine-κ<i>N</i>}copper(I)), [Cu<sub>2</sub>Cl<sub>2</sub>(C<sub>8</sub>H<sub>9</sub>NS)<sub>2</sub>], and di-μ-bromido-bis-({2-[(η-2,3)-(prop-2-en-1-yl)sulfan-yl]pyridine-κ<i>N</i>}copper(I)), [Cu<sub>2</sub>Br<sub>2</sub>(C<sub>8</sub>H<sub>9</sub>NS)<sub>2</sub>], were obtained by alternating-current electrochemical synthesis starting from an ethano-lic solution of 2-[(prop-2-en-1-yl)sulfan-yl]pyridine (<i>Psup</i  ...[more]

Similar Datasets

Unknown (E)-1-[4-(Methyl-sulfan-yl)phen-yl]-3-phenyl-prop-2-en-1-one.
| S-EPMC2961704 | biostudies-literature
Unknown 3,3-Bis(methyl-sulfan-yl)-1-(4-nitro-phen-yl)prop-2-en-1-one.
| S-EPMC3772470 | biostudies-literature
Unknown (E)-3-(4-Fluoro-phen-yl)-1-[4-(methyl-sulfan-yl)phen-yl]prop-2-en-1-one.
| S-EPMC2959522 | biostudies-literature
Unknown (E)-1-(3,4-Dimeth-oxy-phen-yl)-3-[4-(methyl-sulfan-yl)phen-yl]prop-2-en-1-one.
| S-EPMC3200737 | biostudies-literature
Unknown (2E)-3-(6-Meth-oxy-naphthalen-2-yl)-1-[4-(methyl-sulfan-yl)phen-yl]prop-2-en-1-one.
| S-EPMC3394057 | biostudies-literature
Unknown 2-(Benzyl-sulfan-yl)pyridine N-oxide.
| S-EPMC2961086 | biostudies-literature
Unknown 2-[(4-Chloro-benz-yl)sulfan-yl]-4-(2-methyl-prop-yl)-6-(phenyl-sulfan-yl)pyrimidine-5-carbonitrile.
| S-EPMC3393322 | biostudies-literature
Unknown 1-[4-(Prop-2-en-1-yl-oxy)benz-yl]-2-[4-(prop-2-en-1-yl-oxy)phen-yl]-1H-benzimidazole.
| S-EPMC3588921 | biostudies-literature
Unknown 2-(Phenyl-sulfan-yl)pyridine-3-carboxylic acid.
| S-EPMC2971425 | biostudies-literature
Unknown (2E)-1-(4,4''-Difluoro-5'-meth-oxy-1,1':3',1''-terphenyl-4'-yl)-3-[4-(methyl-sulfan-yl)phen-yl]prop-2-en-1-one.
| S-EPMC3414306 | biostudies-literature