Synthesis and absolute structure of (R)-2-(benzyl-selan-yl)-1-phenyl-ethanaminium hydrogen sulfate monohydrate: crystal structure and Hirshfeld surface analyses.

ABSTRACT: A hydrogen sulfate salt, C₁₅H₁₈NSe⁺·HSO₄ ^-·H₂O or [BnSeCH₂CH(Ph)NH₃ ⁺](HSO₄ ^-), of a chiral selenated amine (R)-2-(benzyl-selan-yl)-1-phenyl-ethan-amine (BnSeCH₂CH(Ph)NH₂) has been synthesized and characterized by elemental analysis,¹H and ¹³C{¹H} NMR, FT-IR analysis, and single-crystal X-ray diffraction studies. The title salt crystallizes in the monohydrate form in the non-centrosymmetric monoclinic P2₁ space group. The cation is somewhat W shaped with the dihedral angle between the two aromatic rings being 60.9 (4)°. The carbon atom attached to the amine nitro-gen atom is chiral and in the

SUBMITTER: Rajegowda HR 

PROVIDER: S-EPMC8587982 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature