Crystal structures of Zn(cyclam)I₂ (second monoclinic polymorph) and Zn(cyclam)I(I₃).

ABSTRACT: The asymmetric unit of the first title compound iodido-(1,4,8,11-tetra-aza-cyclo-tetra-decane-κ⁴ N ¹,N ⁴,N ⁸,N ¹¹)zinc(II) iodide, [ZnI(C₁₀H₂₄N₄)]I, I, consists of the zinc-cyclam macrocyclic cation with one iodide anion coordinated to the metal ion [Zn-I = 2.6619 (5) Å] and the second present as a counter-ion. The asymmetric unit of the second title compound iodido-(1,4,8,11-tetra-aza-cyclo-tetra-decane-κ⁴ N ¹,N ⁴,N ⁸,N ¹¹)zinc(II) triiodide, [ZnI(C₁₀H₂₄N₄)]I₃, II, consists of half of the centrosymmetric macrocyclic cation, in which the

SUBMITTER: Gavrish SP 

PROVIDER: S-EPMC8587993 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature