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Novel Ionic Conducting Composite Membrane Based on Polymerizable Ionic Liquids.


ABSTRACT: In this work, the design and characterization of new supported ionic liquid membranes, as medium-temperature polymer electrolyte membranes for fuel-cell application, are described. These membranes were elaborated by the impregnation of porous polyimide Matrimid® with different synthesized protic ionic liquids containing polymerizable vinyl, allyl, or methacrylate groups. The ionic liquid polymerization was optimized in terms of the nature of the used (photo)initiator, its quantity, and reaction duration. The mechanical and thermal properties, as well as the proton conductivities of the supported ionic liquid membranes were analyzed in dynamic and static modes, as a function of the chemical structure of the protic ionic liquid. The obtained membranes were found to be flexible with Young's m

SUBMITTER: Kobzar YL 

PROVIDER: S-EPMC8588533 | biostudies-literature | 2021 Oct

REPOSITORIES: biostudies-literature