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Complete denitrification of nitrate and nitrite to N2 gas by samarium(II) iodide.


ABSTRACT: The reduction of nitrogen oxides (NxOyn-) to dinitrogen gas by samarium(ii) iodide is reported. The polyoxoanions nitrate (NO3-) and nitrite (NO2-), as well as nitrous oxide (N2O) and nitric oxide (NO) were all shown to react with stoichiometric amounts of SmI2 in THF for the complete denitrification to N2.

SUBMITTER: Marks WR 

PROVIDER: S-EPMC8590380 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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Complete denitrification of nitrate and nitrite to N<sub>2</sub> gas by samarium(II) iodide.

Marks Walker R WR   Baumgardner Douglas F DF   Reinheimer Eric W EW   Gilbertson John D JD  

Chemical communications (Cambridge, England) 20200901 77


The reduction of nitrogen oxides (NxOyn-) to dinitrogen gas by samarium(ii) iodide is reported. The polyoxoanions nitrate (NO3-) and nitrite (NO2-), as well as nitrous oxide (N2O) and nitric oxide (NO) were all shown to react with stoichiometric amounts of SmI2 in THF for the complete denitrification to N2. ...[more]

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