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ABSTRACT:
SUBMITTER: Koley D
PROVIDER: S-EPMC8596456 | biostudies-literature | 2021 Nov
REPOSITORIES: biostudies-literature
Koley Debasis D De Sriman S Sivendran Nardana N Gooßen Lukas J LJ
Chemistry (Weinheim an der Bergstrasse, Germany) 20210920 61
In a combined experimental and computational study, the isomerization activity of the dinuclear palladium(I) complex [Pd<sup>I</sup> (μ-Br)(P<sup>t</sup> Bu<sub>3</sub> )]<sub>2</sub> towards allyl arenes, esters, amides, ethers, and alcohols has been investigated. The calculated energy profiles for catalyst activation for two alternative dinuclear and mononuclear catalytic cycles, and for catalyst deactivation are in good agreement with the experimental results. Comparison of experimentally obs ...[more]