Influence of Hydrotropes on the Solubilities and Diffusivities of Redox-Active Organic Compounds for Aqueous Flow Batteries.

ABSTRACT: In this study, we explored the extent to which hydrotropes can be used to increase the aqueous solubilities of redox-active compounds previously used in flow batteries. We measured how five hydrotropes influenced the solubilities of five redox-active compounds already soluble in aqueous electrolytes (≥0.5 M). The solubilities of the compounds varied as a function of hydrotrope type and concentration, with larger solubility changes observed at higher hydrotrope concentrations. 4-OH-TEMPO underwent the largest solubility increase (1.18 ± 0.04 to 1.99 ± 0.12 M) in 20 weight percent sodium xylene sulfonate. The presence of a hydrotrope in solution decreased the diffusion coefficients of 4-OH-TEMPO and 4,5-dihydroxy-1,3-benzenedisulfonate, which was likely due to the increased solution viscosit

SUBMITTER: Cheng Y 

PROVIDER: S-EPMC8600646 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature