Direct observation of one-dimensional disordered diffusion channel in a chain-like thermoelectric with ultralow thermal conductivity.

ABSTRACT: Structural disorder, highly effective in reducing thermal conductivity, is important in technological applications such as thermal barrier coatings and thermoelectrics. In particular, interstitial, disordered, diffusive atoms are common in complex crystal structures with ultralow thermal conductivity, but are rarely found in simple crystalline solids. Combining single-crystal synchrotron X-ray diffraction, the maximum entropy method, diffuse scattering, and theoretical calculations, here we report the direct observation of one-dimensional disordered In¹⁺ chains in a simple chain-like thermoelectric InTe, which contains a significant In¹⁺ vacancy along with interstitial indium sites. Intriguingly, the disordered In¹⁺ chains undergo a static-dynamic transitio

SUBMITTER: Zhang J 

PROVIDER: S-EPMC8602660 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature