Exciton Delocalization Counteracts the Energy Gap: A New Pathway toward NIR-Emissive Dyes.

ABSTRACT: Exciton coupling between the transition dipole moments of ordered dyes in supramolecular assemblies, so-called J/H-aggregates, leads to shifted electronic transitions. This can lower the excited state energy, allowing for emission well into the near-infrared regime. However, as we show here, it is not only the excited state energy modifications that J-aggregates can provide. A bay-alkylated quaterrylene was synthesized, which was found to form J-aggregates in 1,1,2,2-tetrachloroethane. A combination of superradiance and a decreased nonradiative relaxation rate made the J-aggregate four times more emissive than the monomeric counterpart. A reduced nonradiative relaxation rate is a nonintuitive consequence following the 180 nm (3300 cm^-1) red-shift of the J-aggregate in comparison

SUBMITTER: Cravcenco A 

PROVIDER: S-EPMC8603381 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature