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One-dimensional core-shell motif nanowires with chemically-bonded transition metal sulfide-carbon heterostructures for efficient sodium-ion storage.


ABSTRACT: Herein, a chemical-vapor deposition-like strategy was developed for the synthesis of versatile core-shell transition metal sulfide (TMS)@carbon nanowires with chemically-bonded heterostructures and significantly improved electrochemical performance. The morphological evolution observations revealed the simultaneous growth of TMS nanowires and their bonding with an ultrathin carbon layer. The resulting core-shell heterostructured nanowires possessed notable advantages, including fast ion/electron diffusion rates, improved conductivity, and chemical/mechanical stability, thereby leading to remarkable reversible capacity, rate capability, and cycling stability for Na-ion storage applications. The in situ transmission electron microscopy and in situ X-ray diffraction studies for FeS@C demonstr

SUBMITTER: Wei P 

PROVIDER: S-EPMC8612380 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature