Development of Long Wavelength Light-Absorptive Homopolymers Based on Pentaazaphenalene by Regioselective Oxidative Polymerization.

ABSTRACT: We report the synthesis and absorption properties of homopolymers consisting of 1,3,4,6,9b-pentaazaphenalene (5AP). Oxidative polymerization in the Scholl reaction was accomplished, and various lengths of homopolymers can be isolated. It should be noted that we scarcely observed the generation of structural isomers at the connecting points, which is often observed in this type of reaction. Therefore, we were able to evaluate electronic structures of the synthesized homopolymers. In addition, it was observed that absorption bands were obtained in the longer wavelength region than the monomer. The computer calculation suggests that the highest occupied molecular orbital (HOMO) energy levels could be lowered by electronic interaction through spatially-separated HOMOs of 5AP. Moreover, we can evaluate the extension of the conjugated system through the meta-substituted skeleton and distance dependency of the main-chain conjugation.

SUBMITTER: Watanabe H 

PROVIDER: S-EPMC8619047 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature