Reversing sintering effect of Ni particles on γ-Mo₂N via strong metal support interaction.

ABSTRACT: Reversing the thermal induced sintering phenomenon and forming high temperature stable fine dispersed metallic centers with unique structural and electronic properties is one of the ever-lasting targets of heterogeneous catalysis. Here we report that the dispersion of metallic Ni particles into under-coordinated two-dimensional Ni clusters over γ-Mo₂N is a thermodynamically favorable process based on the AIMD simulation. A Ni-4nm/γ-Mo₂N model catalyst is synthesized and used to further study the reverse sintering effect by the combination of multiple in-situ characterization methods, including in-situ quick XANES and EXAFS, ambient pressure XPS and environmental SE/STEM etc. The under-coordinated two-dimensional layered Ni clusters on molybdenum nitride support genera

SUBMITTER: Lin L 

PROVIDER: S-EPMC8632928 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature