Enhanced surface area and reduced pore collapse of methylated, imine-linked covalent organic frameworks.

ABSTRACT: Covalent Organic Frameworks (COFs) are thermally and chemically stable, nanoporous materials with high surface areas, making them interesting for a large variety of applications including energy storage, gas separation, catalysis and chemical sensing. However, pore blocking and pore collapse may limit their performance. Reducing the capillary forces by using solvents with low surface tension, like supercritical CO₂, for activation, and the introduction of bulky isopropyl/methoxy groups were found to reduce pore collapse. Herein, we present an easy-to-use alternative that involves the combination of a new, methylated building block (2,4,6-trimethylbenzene-1,3,5-tricarbaldehyde, Me₃TFB) with vacuum drying. Condensation of Me₃TFB with 1,4-phenylenediamine (PA)

SUBMITTER: Dautzenberg E 

PROVIDER: S-EPMC8638808 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature