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Precise Thermoplastic Processing of Graphene Oxide Layered Solid by Polymer Intercalation.

ABSTRACT: The processing capability is vital for the wide applications of materials to forge structures as-demand. Graphene-based macroscopic materials have shown excellent mechanical and functional properties. However, different from usual polymers and metals, graphene solids exhibit limited deformability and processibility for precise forming. Here, we present a precise thermoplastic forming of graphene materials by polymer intercalation from graphene oxide (GO) precursor. The intercalated polymer enables the thermoplasticity of GO solids by thermally activated motion of polymer chains. We detect a critical minimum containing of intercalated polymer that can expand the interlayer spacing exceeding 1.4 nm to activate thermoplasticity, which becomes the criteria for thermal plastic forming of GO solids. By thermoplastic forming, the flat GO-composite films are forged to Gaussian curved shapes and imprinted to have surface relief patterns with size precision down to 360 nm. The plastic-formed structures maintain the structural integration with outstanding electrical (3.07 × 10⁵ S m^-1) and thermal conductivity (745.65 W m^-1 K^-1) after removal of polymers. The thermoplastic strategy greatly extends the forming capability of GO materials and other layered materials and promises versatile structural designs for more broad applications.

SUBMITTER: Li Z

PROVIDER: S-EPMC8643290 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature

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Precise Thermoplastic Processing of Graphene Oxide Layered Solid by Polymer Intercalation.

Li Zeshen Z Guo Fan F Pang Kai K Lin Jiahao J Gao Qiang Q Chen Yance Y Chang Dan D Wang Ya Y Liu Senping S Han Yi Y Liu Yingjun Y Xu Zhen Z Gao Chao C

Nano-micro letters 20211204 1

The processing capability is vital for the wide applications of materials to forge structures as-demand. Graphene-based macroscopic materials have shown excellent mechanical and functional properties. However, different from usual polymers and metals, graphene solids exhibit limited deformability and processibility for precise forming. Here, we present a precise thermoplastic forming of graphene materials by polymer intercalation from graphene oxide (GO) precursor. The intercalated polymer enabl ...[more]

PMID: 34862936

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Project description:Solid-state shear pulverization (SSSP) is an alternative polymer processing technique based on twin-screw extrusion with a continuous cooling system. In SSSP, low-temperature mechanochemistry modifies the macromolecular architecture and morphology, which in turn leads to physical property changes in the material. While a wide range of homopolymers, polymer blends, and polymer (nano)composites have been previously developed with SSSP, a fundamental understanding of how mechanochemistry affects polymer chain architecture and structure, and in turn, material properties, has not been elucidated. This paper conducts a systematic processing-structure-property relationship investigation of 10 thermoplastic polymers with varying properties, as they are subjected to consistent SSSP mechanochemical pulverization and nanocomposite compounding. Structural, mechanical, and thermal characteristics of the neat polymers are correlated to their response to SSSP by way of process covariants. Further, we investigate how SSSP processing parameters cause structural changes such as molecular weight reduction and filler dispersion level, which in turn dictate system properties like melt viscosity and thermal stability. Mechanochemical engagement with a high degree of physical contact during pulverization and compounding, characterized by the SSSP covariants exhibiting specific mechanical energy values above 4 kJ/g and an average screw temperature above 20 °C, is ensured when polymers have a glass transition temperature below the processing temperature (<50 °C) and high toughness (>40 MPa). Crystallinity and low thermal diffusivity (<0.2 mm2/s) are additional factors for engaged SSSP processing. Chain scission is an unavoidable outcome of SSSP, though the associated molecular weight reduction was <10% for 7 out of 10 polymers. The elucidated processing-structure-property relationships would allow the SSSP process for a given polymer system to be tailored to the specific needs for molecular structure alterations and performance improvements.

Dataset Information

Precise Thermoplastic Processing of Graphene Oxide Layered Solid by Polymer Intercalation.

Publications

Precise Thermoplastic Processing of Graphene Oxide Layered Solid by Polymer Intercalation.

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