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The first coordination complex of (5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra-hydro-[1,2,4]triazolo[1,5-a]pyrimidin-6-amine with zinc(II) acetate-chloride.


ABSTRACT: The title complex, systematic name catena-poly[[[acetato-chlorido-zinc(II)]-μ-(5R,6R,7S)-5-(furan-2-yl)-7-phenyl-4,5,6,7-tetra-hydro-[1,2,4]triazolo[1,5-a]py-rimi-din-6-amine] monohydrate], {[Zn(C2H3O2)Cl(C15H15N5O)]·H2O} n , is the first coordination complex in which the neutral tetra-hydro-triazolo-pyrimidine derivative acts as bridging ligand between two zinc mol-ecules. As a result, polymeric chains of the coordination complex are found. The coordination of the zinc metal atom occurs with the lone pairs of the triazolo nitro-gen atom and amino group. The positive charge of the zinc atom is compensated by the chlorine anion and deprotonated acetic acid. The c

SUBMITTER: Shyshkina MO 

PROVIDER: S-EPMC8647737 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature