Unknown

Dataset Information

0

Stereodivergent Access to Trisubstituted Alkenylboronate Esters through Alkene Isomerization.


ABSTRACT: We report an efficient method for the preparation of synthetically valuable trisubstituted alkenylboronate esters through alkene isomerization of their readily available 1,1-disubstituted regioisomeric counterparts. Either stereoisomer of the target alkenylboronate motif can be obtained at will from the same starting material by employing different isomerization catalysts.

SUBMITTER: Segura L 

PROVIDER: S-EPMC8650100 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature

altmetric image

Publications

Stereodivergent Access to Trisubstituted Alkenylboronate Esters through Alkene Isomerization.

Segura Lucas L   Massad Itai I   Ogasawara Masamichi M   Marek Ilan I  

Organic letters 20211112 23


We report an efficient method for the preparation of synthetically valuable trisubstituted alkenylboronate esters through alkene isomerization of their readily available 1,1-disubstituted regioisomeric counterparts. Either stereoisomer of the target alkenylboronate motif can be obtained at will from the same starting material by employing different isomerization catalysts. ...[more]

Similar Datasets

| S-EPMC11021481 | biostudies-literature
| S-EPMC11774263 | biostudies-literature
| S-EPMC11701836 | biostudies-literature
| S-EPMC5347846 | biostudies-literature
| S-EPMC5705238 | biostudies-literature
| S-EPMC8456971 | biostudies-literature
| S-EPMC9431960 | biostudies-literature
| S-EPMC8278922 | biostudies-literature
| S-EPMC11491460 | biostudies-literature
| S-EPMC7608664 | biostudies-literature