Ozone chemistry in western U.S. wildfire plumes.

ABSTRACT: Wildfires are a substantial but poorly quantified source of tropospheric ozone (O₃). Here, to investigate the highly variable O₃ chemistry in wildfire plumes, we exploit the in situ chemical characterization of western wildfires during the FIREX-AQ flight campaign and show that O₃ production can be predicted as a function of experimentally constrained OH exposure, volatile organic compound (VOC) reactivity, and the fate of peroxy radicals. The O₃ chemistry exhibits rapid transition in chemical regimes. Within a few daylight hours, the O₃ formation substantially slows and is largely limited by the abundance of nitrogen oxides (NO_x). This finding supports previous observations that O₃ formation is enhanced wh

SUBMITTER: Xu L 

PROVIDER: S-EPMC8654285 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature