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Ozone chemistry in western U.S. wildfire plumes.


ABSTRACT: [Figure: see text].

SUBMITTER: Xu L 

PROVIDER: S-EPMC8654285 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature

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Ozone chemistry in western U.S. wildfire plumes.

Xu Lu L   Crounse John D JD   Vasquez Krystal T KT   Allen Hannah H   Wennberg Paul O PO   Bourgeois Ilann I   Brown Steven S SS   Campuzano-Jost Pedro P   Coggon Matthew M MM   Crawford James H JH   DiGangi Joshua P JP   Diskin Glenn S GS   Fried Alan A   Gargulinski Emily M EM   Gilman Jessica B JB   Gkatzelis Georgios I GI   Guo Hongyu H   Hair Johnathan W JW   Hall Samuel R SR   Halliday Hannah A HA   Hanisco Thomas F TF   Hannun Reem A RA   Holmes Christopher D CD   Huey L Gregory LG   Jimenez Jose L JL   Lamplugh Aaron A   Lee Young Ro YR   Liao Jin J   Lindaas Jakob J   Neuman J Andrew JA   Nowak John B JB   Peischl Jeff J   Peterson David A DA   Piel Felix F   Richter Dirk D   Rickly Pamela S PS   Robinson Michael A MA   Rollins Andrew W AW   Ryerson Thomas B TB   Sekimoto Kanako K   Selimovic Vanessa V   Shingler Taylor T   Soja Amber J AJ   St Clair Jason M JM   Tanner David J DJ   Ullmann Kirk K   Veres Patrick R PR   Walega James J   Warneke Carsten C   Washenfelder Rebecca A RA   Weibring Petter P   Wisthaler Armin A   Wolfe Glenn M GM   Womack Caroline C CC   Yokelson Robert J RJ  

Science advances 20211208 50


Wildfires are a substantial but poorly quantified source of tropospheric ozone (O<sub>3</sub>). Here, to investigate the highly variable O<sub>3</sub> chemistry in wildfire plumes, we exploit the in situ chemical characterization of western wildfires during the FIREX-AQ flight campaign and show that O<sub>3</sub> production can be predicted as a function of experimentally constrained OH exposure, volatile organic compound (VOC) reactivity, and the fate of peroxy radicals. The O<sub>3</sub> chemi  ...[more]

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