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Room-Temperature Spin Crossover in a Solution of Iron(II) Complexes with N,N'-Disubstituted Bis(pyrazol-3-yl)pyridines.

ABSTRACT: Here, we report a combined study of the effects of two chemical modifications to an N,N'-disubstituted bis(pyrazol-3-yl)pyridine (3-bpp) and of different solvents on the spin-crossover (SCO) behavior in otherwise high-spin iron(II) complexes by solution NMR spectroscopy. The observed stabilization of the low-spin state by electron-withdrawing substituents in the two positions of the ligand that induce opposite electronic effects in SCO-active iron(II) complexes of isomeric bis(pyrazol-1-yl)pyridines (1-bpp) was previously hidden by NH functionalities in 3-bpp precluding the molecular design of SCO compounds with this family of ligands. With the recent SCO-assisting substituent design, the uncovered trends converged toward the first iron(II) complex of N,N'-disubstituted 3-bpp to undergo an almost complete SCO centered at room temperature in a less polar solvent of a high hydrogen-bond acceptor ability.

SUBMITTER: Aleshin DY 

PROVIDER: S-EPMC8655922 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature

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Room-Temperature Spin Crossover in a Solution of Iron(II) Complexes with <i>N</i>,<i>N</i>'-Disubstituted Bis(pyrazol-3-yl)pyridines.

Aleshin Dmitry Yu DY   Nikovskiy Igor I   Novikov Valentin V VV   Polezhaev Alexander V AV   Melnikova Elizaveta K EK   Nelyubina Yulia V YV  

ACS omega 20211122 48

Here, we report a combined study of the effects of two chemical modifications to an <i>N</i>,<i>N</i>'-disubstituted bis(pyrazol-3-yl)pyridine (3-bpp) and of different solvents on the spin-crossover (SCO) behavior in otherwise high-spin iron(II) complexes by solution NMR spectroscopy. The observed stabilization of the low-spin state by electron-withdrawing substituents in the two positions of the ligand that induce opposite electronic effects in SCO-active iron(II) complexes of isomeric bis(pyra  ...[more]

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