Atomically Dispersed Fe-Co Bimetallic Catalysts for the Promoted Electroreduction of Carbon Dioxide.

ABSTRACT: The electroreduction reaction of CO₂ (ECO₂RR) requires high-performance catalysts to convert CO₂ into useful chemicals. Transition metal-based atomically dispersed catalysts are promising for the high selectivity and activity in ECO₂RR. This work presents a series of atomically dispersed Co, Fe bimetallic catalysts by carbonizing the Fe-introduced Co-zeolitic-imidazolate-framework (C-Fe-Co-ZIF) for the syngas generation from ECO₂RR. The synergistic effect of the bimetallic catalyst promotes CO production. Compared to the pure C-Co-ZIF, C-Fe-Co-ZIF facilitates CO production with a CO Faradaic efficiency (FE) boost of 10%, with optimal FE_CO of 51.9%, FE_H2 of 42.4% at - 0.55 V, and CO current density of 8.0 mA cm

SUBMITTER: Chen Z 

PROVIDER: S-EPMC8664923 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature