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Valorization of winery and distillery by-products by hydrothermal carbonization.

ABSTRACT: This work aims at finding an alternative strategy to manage the waste generated by the winemaking industry to obtain a solid biofuel and phenolic compounds. The effect of temperature (180-260 °C), residence time (1-7 h), and biomass-to-liquid ratio (0.05-0.25) on the co-hydrothermal carbonization of vine pruning and exhausted grape pomace, by using vinasse as moisture source, is studied. The effect of the variables is investigated and optimized using the Box-Behnken design of response surface methodology to maximize mass yield, fuel ratio, energy densification yield and phenols extraction yield and to minimize energy consumption. The statistical analysis shows that the carbonization temperature is a crucial parameter of the process, decreasing the product yield on one hand and improving the quality of hydrochar on the other. At the optimal conditions (246.3 °C, 1.6 h, 0.066), an hydrochar yield of 52.64% and a calorific value of 24.1 MJ/kg were obtained. Moreover, the analysis of the H/C and O/C ratios of hydrochars demonstrates that carbonisation significantly improves the fuel properties of solid biofuel. Liquid by-products obtained from the HTC process are found to contain high concentrations of organic matter but the BOD/COD ratios suggest their potential valorization by biological methods.

SUBMITTER: Barbanera M

PROVIDER: S-EPMC8671441 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature

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Valorization of winery and distillery by-products by hydrothermal carbonization.

Barbanera Marco M Cardarelli Alessandro A Carota Eleonora E Castellini Marco M Giannoni Tommaso T Ubertini Stefano S

Scientific reports 20211214 1

This work aims at finding an alternative strategy to manage the waste generated by the winemaking industry to obtain a solid biofuel and phenolic compounds. The effect of temperature (180-260 °C), residence time (1-7 h), and biomass-to-liquid ratio (0.05-0.25) on the co-hydrothermal carbonization of vine pruning and exhausted grape pomace, by using vinasse as moisture source, is studied. The effect of the variables is investigated and optimized using the Box-Behnken design of response surface me ...[more]

PMID: 34907329

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Project description:Background: Hydrothermal carbonization (HTC) of dairy processing waste was performed to investigate the effect of temperature and initial pH on the yield and composition of the solid (hydrochar) and liquor produced. All hydrochars met the EU requirements of organo-mineral solid fertilizers defined in the Fertilizing Products Regulation in terms of phosphorus (P) and mineral content. Methods: Laboratory scale HTC was performed using pressurized reactors, and the products (solid and liquid) were collected, stored and analyzed for elemental composition and nutrient content using Inductively coupled plasma optical emission spectroscopy (ICP-OES), ultraviolet-visible spectrophotometry (UV-Vis) and other analytic techniques. Results: Maximum hydrochar yield (60.67%) was observed at T=180℃ and pH=2.25, whereas the maximum P-recovery was 80.38% at T=220℃ and pH=4.6. The heavy metal content of the hydrochars was mostly compliant with EU limitations, except for Ni at T=220℃ and pH=8.32. Meanwhile, further study of Chromium (Cr) species is essential to assess the fertilizer quality of the hydrochars. For the liquid product, the increase in temperature beyond 200℃, coupled with an increase in initial acidity (pH=2.25) drove P into the liquor. Simultaneously, increasing HTC temperature and acidity increased the concentration of NO 3 - and NH 4 + in the liquid products to a maximum of 278 and 148 mg/L, respectively, at T=180℃ and pH=4.6. Furthermore, no direct relation between final pH of liquor and NH 4 + concentration was observed. Conclusions: HTC allows for the production of hydrochar as a potential fertilizer material that requires further processing. Adjusting HTC conditions enhanced P-recovery in the hydrochar, while retrieving higher nitrate concentrations in the liquid product. Optimizing HTC for the production of qualified hydrochars requires further treatment of Cr content, studying the availability of P in the products and enhancing the hydrochar yield for economic feasibility.

Project description:BackgroundBiomass fuel has been used to supply heat or crude materials in industry to replace the traditional fossil fuel which was one of the chief causes of climate warming. However, the large-scale utilization of biomass fuel was restricted due to the low density and high hydrophilicity of biomass, which causes the problem of transportation and storage. Therefore, pelletization of biomass was used to improve its fuel density. At present, the biomass pellet was widely used to supply heat, gas or electricity generation via gasification, which supplied clean and sustainable energy for industry. However, the energy consumption during pelletization and high hydrophilicity of pellets were still the problem for the large-scale application of biomass pellet. In this study, hydrothermal carbonization and surfactant played the role of permeation, adsorption and wetting in the solution, which was expected to improve the fuel properties and pelletization effectivity of corn stover.ResultsIn the article, surfactant (PEG400, Span80, SDBS) was chosen to be combined with wet torrefaction to overcome the drawbacks and improve the pelletization and combustion properties of Corn stover (CS). Especially, hydrothermal carbonization (HTC) combined with surfactant improves the yield of solid products and reduces the ash content of solid product, which was beneficial for reducing the ashes of furnace during gasification. Meanwhile, surfactant promotes the formation of pseudo-lignin and the absorption for oil with low O and high C during HTC, which improves the energy density of solid product. Furthermore, the oil in solid product plays the role of lubricant and binder, which reduces the negative effect of high energy consumption, low bulk density and weak pellets strength caused by HTC during pelletization. HTC combined with surfactant improved the hydrophobicity of pellet as well as grindability due to the modification of solid product. Moreover, surfactant combined with HTC improved the combustion characteristic of solid product such as ignition and burning temperature as well as kinetic parameters due to the bio-oil absorbed and the improvement of surface and porosity.ConclusionsThe study supplied a new, less-energy intensive and effective method to improve the pelletization and combustion properties of corn stover via hydrothermal carbonization combined with surfactant, and provided a promising alternative fuel from corn stover .

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Valorization of winery and distillery by-products by hydrothermal carbonization.

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Valorization of winery and distillery by-products by hydrothermal carbonization.

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