Radiolytic redox interplay defines nanomaterial synthesis in liquids.
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ABSTRACT:
SUBMITTER: Ahmed A
PROVIDER: S-EPMC8682990 | biostudies-literature | 2021 Dec
REPOSITORIES: biostudies-literature
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Radiolytic redox interplay defines nanomaterial synthesis in liquids.
Ahmed Auwais A Boyle Erik C EC Kottke Peter A PA Fedorov Andrei G AG
Science advances 20211217 51
Irradiation of a liquid solution generates solvated electrons and radiolysis products, which can lead to material deposition or etching. The chemical environment dictates the dominant reactions. Radiolysis-induced reactions in salt solutions have substantially different results in pure water versus water-ammonia, which extends the lifetime of solvated electrons. We investigate the interplay between transport and solution chemistry via the example of solid silver formation from e-beam irradiation ...[more]
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