One-pot construction of nitrogen-rich polymeric ionic porous networks for effective CO₂ capture and fixation.

ABSTRACT: Facile preparation of ionic porous networks (IPNs) with large and permanent porosity is highly desirable for CO₂ capture and transformation but remains a challenge. Here we report a one-pot base-mediated construction of nitrogen-rich IPNs through a combination of nucleophilic substitution and quaternisation chemistry from H-imidazole. This strategy, as proven by the model reactions of 1H-imidazole or 1-methyl-1H-imidazole with cyanuric chloride, allows for fine regulation of porosity and physicochemical properties, leading to nitrogen-rich IPNs featuring abundant ionic units and radicals. The as-prepared networks, termed IPN-CSUs, efficiently capture CO₂ (80.1 cc g^-1 at 273 K/1 bar) with an ideal CO₂/N₂ selectivity of 139

SUBMITTER: Ai C 

PROVIDER: S-EPMC8689585 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature