Integrated Cr and S poisoning of a La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ (LSCF) cathode for solid oxide fuel cells.

ABSTRACT: Strontium segregation in a La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ (LSCF) electrode reacts with Cr and S in a solid oxide fuel cell (SOFC), which can cause cell performance deterioration. Integrated Cr and S poisoning for LSCF cathodes of SOFC was studied at 800 °C of 200 mA cm^-2 (cathodic) for 20 h. After polarization in Cr and S at 800 °C for 20 h, polarization and ohmic resistances for LSCF were 2.4 Ω cm² and 3.4 Ω cm², which were larger than those for LSCF electrodes after Cr deposition only and S deposition only, respectively. The results illustrated that Cr and S deposition occurred on the surface of LSCF, which could form SrCrO₄ and SrSO₄. Compared to Cr deposition only and S deposi

SUBMITTER: Wang CC 

PROVIDER: S-EPMC8690037 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature