Recovery of valuable metals from mixed spent lithium-ion batteries by multi-step directional precipitation.

ABSTRACT: The novel strategy of multi-step directional precipitation is proposed for recovering valuable metals from the leachate of cathode material obtained by mechanical disassembly from mixed spent lithium-ion batteries. Based on thermodynamics and directional precipitation, Mn²⁺ is selectively precipitated under conditions of MRNM (molar ratio of (NH₄)₂S₂O₈ to Mn²⁺) = 3, pH = 5.5 and 80 °C for 90 min. Ni²⁺ was then selectively precipitated using C₄H₈N₂O₂ under conditions of pH = 6, MRCN (molar ratio of C₄H₈N₂O₂ to Ni²⁺) = 2, 30 °C and 20 min. Then, the pH was adjusted to 10 to precipitate Co²⁺ as Co(OH)₂. Finally, Li⁺ was recovered by Na₂CO₃ at 90 °C. The precipitation rates of Mn, Ni, Co, and Li reached 99.5%, 99.6%, 99.2% and 90%, respectively. The precipitation products with high purity can be used as raw materials for industrial production based on characterization. The economical and efficient recovery process can be applied in industrialized large-scale recycling of spent lithium-ion batteries.

SUBMITTER: Yang X 

PROVIDER: S-EPMC8690296 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature