Construction of activated carbon-supported B₃N₃ doped carbon as metal-free catalyst for dehydrochlorination of 1,2-dichloroethane to produce vinyl chloride.

ABSTRACT: Dehydrochlorination of 1,2-dichloroethane (1,2-DCE) is an important oil-based way for the industrial production of vinyl chloride monomer (VCM), but has proved to be plagued by a high operating temperature and low efficiency. Therefore, environmentally friendly and metal-free catalysts are in high demand for green chemical processes. In view of the stronger electronegativity of borazine (B₃N₃) and convenience of constructing a two-dimensional structure because of the coplanarity of B₃N₃, the acetenyl group, and the benzene ring, herein, we report a novel controllable B₃N₃ doped activated carbon (B,N-ACs) synthesized using B₃N₃-containing arylacetylene resin for dehydrochlorination of 1,2-DCE. The result

SUBMITTER: Chen C 

PROVIDER: S-EPMC8690420 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature