Photo-assisted sequential assembling of uniform metal nanoclusters on semiconductor support.

ABSTRACT: Dispersing metal nanoclusters on the oxide supports is attracting close attention in heterogeneous catalysis, but great challenges still lie in controlling the size and dispersion of nanoclusters due to the inevitable agglomeration. Here, we propose a sequential photochemical deposition strategy named "first store, and then release" to uniformly fabricate the size-controlling noble metal nanoclusters on semiconductor oxides. Using the typical semiconductor TiO₂, the photoexcited electrons can be first stored as reduced species (e.g. Ti³⁺) under irradiation and the Ti³⁺ species can optimize both the nucleation and growth processes in dark reaction, resulting in a uniform dispersing of various noble metals (Au, Pt, Ag etc.) with size diameters of ∼1 nm. The n

SUBMITTER: Wu H 

PROVIDER: S-EPMC8692999 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature