Synthesis of biological based hennotannic acid-based salts over porous bismuth coordination polymer with phosphorous acid tags.

ABSTRACT: In this paper, a novel porous polymer capable of coordinating to bismuth (PCPs-Bi) was synthesized. The Bi-PCPs was then reacted with phosphorous acid to produce a novel polymer PCPs(Bi)N(CH₂PO₃H₂)₂ which is shown to act as an efficient and recyclable catalyst. The mentioned catalyst was applied for the efficient synthesis of new mono and bis naphthoquinone-based salts of piperidine and/or piperazine via the reaction of hennotannic acid with various aldehydes, piperidine and/or piperazine, respectively. The structure of the resulting mono and bis substituted piperazine or piperidine-based naphthoquinone salts was thoroughly characterized spectroscopically. The electrochemical behavior of the products was also investigated. The presented pr

SUBMITTER: Babaee S 

PROVIDER: S-EPMC8693640 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature