Fused sphere carbon monoliths with honeycomb-like porosity from cellulose nanofibers for oil and water separation.

ABSTRACT: Carbon monoliths with a unique hierarchical surface structure from carbonized cellulose nanofibers were synthesized in pursuit of developing carbon materials from sustainable natural resources. Through a 2-step hydrothermal - carbonization method, TEMPO-oxidized cellulose nanofibers were turned into carbon-rich hydrochar embedded with polystyrene latex as template for 80 nm-sized pores in a honeycomb pattern, while the triblock copolymer Pluronic F-127 was used for a dual purpose not reported before: (1) an interface between the cellulose nanofibers and polystyrene particles, as well as (2) act as a secondary template as ∼1 μm micelles that form hollow carbon spheres. The use of nanofibers allowed more contact between the carbon spheres to coalesce into a working monolith while optimizing

SUBMITTER: Ferry MA 

PROVIDER: S-EPMC8693729 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature