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Direct DME synthesis on CZZ/H-FER from variable CO2/CO syngas feeds.


ABSTRACT: Catalyst systems for the conversion of synthesis gas, which are tolerant to fluctuating CO/CO2 gas compositions, have great potential for process-technical applications, related to the expected changes in the supply of synthesis gas. Copper-based catalysts usually used in the synthesis of methanol play an important role in this context. We investigated the productivity characteristics for their application in direct dimethyl ether (DME) synthesis as a function of the CO2/CO x ratio over the complete range from 0 to 1. For this purpose, we compared an industrial Cu/ZnO/Al2O3 methanol catalyst with a self-developed Cu/ZnO/ZrO2 catalyst prepared by a continuous coprecipitation approach. For DME synthesis, catalysts were

SUBMITTER: Wild S 

PROVIDER: S-EPMC8693869 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature