Chemisorption of hydrogen sulfide over copper-based metal-organic frameworks: methanol and UV-assisted regeneration.

ABSTRACT: Three copper-based metal-organic frameworks (MOFs) with different organic linkers were synthesized for the removal of H₂S gas at room temperature. The synthesized MOFs were characterized by microscopic and spectroscopic techniques to understand their structural, functional, and optical properties. The H₂S adsorption capacity of MOFs calculated by column studies followed the trend: 105.6 mg g^-1 (CuBDC) > 27.1 mg g^-1 (CuBTC) > 1.3 mg g^-1 (CuBDC-N) in dry conditions. The adsorption capacity increased in moist conditions due to an easy dissolution and dissociation of H₂S in a film of water. X-ray photoelectron spectroscopy confirmed the presence of sulfur bound to Cu-sites and sulfate ions. The spent MOFs were regenerated by the

SUBMITTER: Gupta NK 

PROVIDER: S-EPMC8694540 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature