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Development of effective potassium acetate extractant.


ABSTRACT: Carboxylates are commonly used in the food and pharmaceutical industry and due to their extensive use, carboxylates present a significant environmental burden. In this context, valine based, heteroditopic receptor 1 was prepared and its ability to bind simultaneously potassium cation and acetate anion in water containing CH3CN solutions was demonstrated. Under liquid-liquid extraction conditions the receptor 1 was capable of extracting hydrophilic AcOK salt from aqueous solution and was proved to be nearly ten times more effective than the equimolar mixture of monotopic receptors. Furthermore, compound 1 could extract one of the most popular nonsteroidal anti-inflammatory drugs, ibuprofen (IbuOK), from relatively dilute aqueous solutions.

SUBMITTER: Zakrzewski M 

PROVIDER: S-EPMC8695828 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature

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Development of effective potassium acetate extractant.

Zakrzewski Maciej M   Załubiniak Dominika D   Piątek Piotr P  

RSC advances 20210316 18


Carboxylates are commonly used in the food and pharmaceutical industry and due to their extensive use, carboxylates present a significant environmental burden. In this context, valine based, heteroditopic receptor 1 was prepared and its ability to bind simultaneously potassium cation and acetate anion in water containing CH<sub>3</sub>CN solutions was demonstrated. Under liquid-liquid extraction conditions the receptor 1 was capable of extracting hydrophilic AcOK salt from aqueous solution and w  ...[more]

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