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Theoretical hydrogen bonding calculations and proton conduction for Eu(iii)-based metal-organic framework.

ABSTRACT: A water-mediated proton-conducting Eu(iii)-MOF has been synthesized, which provides a stable proton transport channel that was confirmed by theoretical calculation. The investigation of proton conduction shows that the conductivity of Eu(iii)-MOF obtained at 353 K and 98% RH is 3.5 × 10^-3 S cm^-1, comparable to most of the Ln(iii)-MOF based proton conductors.

SUBMITTER: Feng L

PROVIDER: S-EPMC8698213 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature

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Theoretical hydrogen bonding calculations and proton conduction for Eu(iii)-based metal-organic framework.

Feng Lu L Zeng Tian-Yu TY Hou Hao-Bo HB Zhou Hong H Tian Jian J

RSC advances 20210322 19

A water-mediated proton-conducting Eu(iii)-MOF has been synthesized, which provides a stable proton transport channel that was confirmed by theoretical calculation. The investigation of proton conduction shows that the conductivity of Eu(iii)-MOF obtained at 353 K and 98% RH is 3.5 × 10<sup>-3</sup> S cm<sup>-1</sup>, comparable to most of the Ln(iii)-MOF based proton conductors. ...[more]

PMID: 35423605

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