Triple oxygen isotope constraints on atmospheric O₂ and biological productivity during the mid-Proterozoic.

ABSTRACT: Reconstructing the history of biological productivity and atmospheric oxygen partial pressure (pO₂) is a fundamental goal of geobiology. Recently, the mass-independent fractionation of oxygen isotopes (O-MIF) has been used as a tool for estimating pO₂ and productivity during the Proterozoic. O-MIF, reported as Δ'¹⁷O, is produced during the formation of ozone and destroyed by isotopic exchange with water by biological and chemical processes. Atmospheric O-MIF can be preserved in the geologic record when pyrite (FeS₂) is oxidized during weathering, and the sulfur is redeposited as sulfate. Here, sedimentary sulfates from the ∼1.4-Ga Sibley Formation are reanalyzed using a detailed one-dimensional photochemical model that includes phys

SUBMITTER: Liu P 

PROVIDER: S-EPMC8713798 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature