Dynamic Surface Reconstruction Unifies the Electrocatalytic Oxygen Evolution Performance of Nonstoichiometric Mixed Metal Oxides.

ABSTRACT: Compositionally versatile, nonstoichiometric, mixed ionic-electronic conducting metal oxides of the form A _n+1B _n O_3n+1 (n = 1 → ∞; A = rare-earth-/alkaline-earth-metal cation; B = transition-metal (TM) cation) remain a highly attractive class of electrocatalysts for catalyzing the energy-intensive oxygen evolution reaction (OER). The current design strategies for describing their OER activities are largely derived assuming a static, unchanged view of their surfaces, despite reports of dynamic structural changes to 3d TM-based perovskites during OER. Herein, through variations in the A- and B-site compositions of A _n+1B _n O_3n+1 oxides (n = 1 (A₂BO₄

SUBMITTER: Samira S 

PROVIDER: S-EPMC8715492 | biostudies-literature | 2021 Dec

REPOSITORIES: biostudies-literature